AMINO ACID DERIVATIVES THAT STABILIZE SECONDARY STRUCTURES OF POLYPEPTIDES. I. SYNTHESIS OF LL-3-AMINO-2-PIPERIDONE-6-CARBOXYLIC ACID (LL-Acp), A NOVEL BETA-TURN-FORMING AMINO ACID

DOI: 10.1016/S0040-4039(00)87699-6

Source and publish data:

Tetrahedron Letters p. 3759 - 3760 (1982)

Update date:2022-08-03

Topics:

Authors:

Kemp, D. S.

Sun, Eric T.

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Article abstract of DOI:10.1016/S0040-4039(00)87699-6

A six-step synthesis is reported of LL-3-amino-2-piperidone-6-carboxylic acid from L-homoserine lactone and the mono-t-butyl ester of N-benzyloxycarbonylaminomalonic acid.Evidence of chiral integrity is discussed.

Full text of DOI:10.1016/S0040-4039(00)87699-6

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