Chemistry Letters p. 1733 - 1734 (1982)
Update date:2022-08-03
Topics:
Tomoda, Shuji
Takeuchi, Yoshito
Nomura, Yujiro
The reaction of ketene acetals with phenyl selenocyanate afforded a new type of compounds, α,α-dioxy-β-phenylseleno carbonitriles (carbonyl-protected α-oxo carbonitriles), in good yields.Oxidation of these vicinalcyanoselenenylation products gave β,γ-unsaturated α,α-dioxy carbonitriles in excellent yields.
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