Journal of the American Chemical Society p. 5047 - 5053 (1983)
Update date:2022-08-05
Topics:
Agopovich
Gillies
In this paper, preliminary studies with the ozonolyses of trifluoroethylene and 1,1-difluoroethylene are extended to low-temperature reaction conditions ( minus 78 and minus 95 C), and a complete product analysis is reported for both olefins. The isolation and identification of two previously unknown cyclopropane isomers, cis- and trans-1,1,2,3-tetrafluorocyclopropane, is discussed. The characterization of an unknown component in the trifluoroethylene ozonolyses as cis-1,2-difluoroethylene ozonide permits a determination of the cis-/trans-1,2-difluoroethylene ozonide ratio in these reactions. Results from aldehyde insertion experiments in the ozonolysis of CH//2 equals CF//2 and CF//2 equals CF//2 are related to the ozonide and epoxide mechanisms.
View MoreTianjin Jiuri New Materials Co., Ltd.
Contact:+86-22-58889220
Address:C-5/6, Vison Hill, No.1 Gonghua Road, Huayuan Hi-tech Park, Tianjin, China.
Contact:86-0510-85133006
Address:hubin road NO157
HEZE KINGVOLT CHEMICAL CO., LTD
Contact:86-573-82118911
Address:Juancheng Industry Park
Shijiazhuang City Xiehe Pharmaceutical Co., Ltd
Contact:+86-311-80817929
Address:Shangzhuang,Shijiazhuang,China
Contact:+(852) 301-98033
Address:Flat C, 23/F, Lucky Plaza, 315-321 Lockhart Road, Wan Chai, Hong Kong
Doi:10.1016/j.jorganchem.2005.02.036
(2005)Doi:10.1016/j.bmc.2013.06.069
(2013)Doi:10.1016/S0040-4039(00)60042-4
(1992)Doi:10.1021/acs.joc.1c00323
(2021)Doi:10.1016/j.polymer.2013.07.021
(2013)Doi:10.1021/jo4012943
(2013)