THIA-ACYLIMINIUM - OLEFIN CYCLIZATIONS

DOI: 10.1016/0040-4020(82)80103-8

Source and publish data:

Tetrahedron p. 3255 - 3266 (1982)

Update date:2022-07-29

Topics:

Authors:

Hamersma, J. A. M.

Speckamp, W. N.

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Article abstract of DOI:10.1016/0040-4020(82)80103-8

Regioselective NaBH4/H(1+)-reduction of thiazolidine-diones 3 - 8 substituted at the nitrogen atom with different ?-nucleophiles affords hydroxylactams 9 - 14 in good yields.The latter compounds are excellent precursors for the α-acyliminium ion 16 and ca

Full text of DOI:10.1016/0040-4020(82)80103-8

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