Ene Reaction Mechanisms. 1. Chirality Transfer to the Enophile 4-Methyl-N-sulfinylbenzenesulfonamide

Article abstract of DOI:10.1021/jo00165a009

The ene reaction of (S)-(+)-3-phenyl-1-butene (1) with N-sulfinyl-p-toluenesulfonamide (2) leads to the optically active (E)-2-alkenesulfinamide 3.This corresponds to a chirality transfer from the chiral carbon center in 1 to the sulfur atom of the produc