RING OPENING REACTIONS OF THIIRANES WITH GROUP IV B ORGANOMETALLICS: A NEW REGIOSELECTIVE ROUTE TO β-AMINO AND β-CYANIDE THIOLS.

DOI: 10.1016/S0040-4039(00)81911-5

Source and publish data:

Tetrahedron Letters p. 2311 - 2314 (1983)

Update date:2022-07-30

Topics:

Authors:

Taddei, Maurizio

Papini, Annamaria

Fiorenza, Mariella

Ricci, Alfredo

Seconi, Giancarlo

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Article abstract of DOI:10.1016/S0040-4039(00)81911-5

Regioselective opening of the thiirane ring occurs spontaneously with Group IV B organometallics such as Me3SnNR2 and under the catalytic action of AlCl3 with Me3SiCN, affording difunctional thiols.

Full text of DOI:10.1016/S0040-4039(00)81911-5

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