Stereochemistry of Vinyl Cuprate Additions to Carbohydrate-Derived Enones and α,β-Unsaturated Esters

DOI: 10.1016/S0040-4039(00)81891-2

Source and publish data:

Tetrahedron Letters p. 2231 - 2234 (1983)

Update date:2022-08-03

Topics:

Authors:

Roush, William R.

Lesur, Brigitte M.

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Article abstract of DOI:10.1016/S0040-4039(00)81891-2

Vinylic cuprate reagents add with excellent diastereoselectivity (>10:1) to carbohydrate derived enones and α,β-unsaturated esters.The stereochemical outcome of these transformations is consistent with a Felkin-type addition pathway.

Full text of DOI:10.1016/S0040-4039(00)81891-2

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