Tetrahedron Letters p. 2231 - 2234 (1983)
Update date:2022-08-03
Topics:
Roush, William R.
Lesur, Brigitte M.
Vinylic cuprate reagents add with excellent diastereoselectivity (>10:1) to carbohydrate derived enones and α,β-unsaturated esters.The stereochemical outcome of these transformations is consistent with a Felkin-type addition pathway.
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