Tetrahedron p. 3203 - 3216 (1989)
Update date:2022-08-03
Topics:
Wasserman, Harry H.
Dion, Robert P.
Fukuyama, James
1-Piperidino-1-trimethylsilyloxycyclopropane and the corresponding 1-hydroxy-1-piperidinocyclopropane, conveniently prepared from the piperidide of 3-chloropropionic acid, react as cyclopropanone equivalents with various nucleophiles.Use of these derivatives in the formation of pyrroles, pyrrolines and pyrrolizidines is described.The rearrangement of dicyclopropyl ketimines is explored.
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