Journal of Organic Chemistry p. 4940 - 4944 (1983)
Update date:2022-08-03
Topics:
Rubottom, George M.
Gruber, John M.
Marrero, Roberto
Juve, Henrik D.
Kim, Wan Chong
Alkyl trimethylsilyl ketene acetals generated from either esters or lactones react with lead(IV) acetate (LTA) or lead(IV) benzoate (LTB) to afford useful yields of the corresponding α-carboyloxy esters and α-carboyloxy lactones.Yields of the reaction products are optimized by use of the appropriate solvent (methylene chloride or benzene) during oxidation.Alkyl groups such as methyl, ethyl, and tert-butyl are all compatible with the procedure, and lactones containing five-, six-, and seven-membered rings give good yields of oxidation products.
View Morewebsite:http://www.hanwayschem.com
Contact:+86-18502787239(whatsapp)-
Address:18-1-802, Green Garden, Jianghan District, Wuhan 430023, China
Contact:+65 9658 0999
Address:26 Sin Ming Lane, Midview City, #05-118, Singapore 573971
SuZhou Bichal Biological Technology CO.,LTD
Contact:+86-512-68051130
Address:NO.32 huoju road HI-TECH Industrial development zone SuZhou China
Melone Pharmaceutical Co., ltd
Contact:+86-411 82593920, 82593631
Address:No 232, JInma Roda, Development Zone, Dalian, China
Contact:+86-22-26358246
Address:601-4-20, Fujiayuan, Tiantai Road, Hebei District, Tianjin, China
Doi:10.1055/s-0039-1691740
(2020)Doi:10.1021/ic051168u
(2006)Doi:10.1002/ardp.200500102
(2005)Doi:10.1039/P29830000975
(1983)Doi:10.1021/ja010113y
(2001)Doi:10.1016/S0040-4039(00)88196-4
(1983)
