Tetrahedron p. 2989 - 2994 (1983)
Update date:2022-08-04
Topics:
Baldwin, Jack E.
Derome, Andrew E.
Riordan, Peter D.
Carbon-13 NMR has been used to show that the deoxygenation of isocyanates to isonitriles with t-butyldiphenylsilyl lithium proceeds via the intermediates (7 and 8).The silyl carboxamide (1) can be isolated but is thermally unstable rearranging to a mixture of silyl formamides (2).The spectroscopic properties of the silyl carboxamide (1) were found to be substantially different from those previously claimed for such compounds.
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