THE BAEYER-VILLIGER OXIDATION VIA CARBOCATION, OXIDATION OF 7-ACETYL- AND 7-ACETYLPROPELLANES

DOI: 10.1016/S0040-4039(00)88189-7

Source and publish data:

Tetrahedron Letters p. 3639 - 3642 (1983)

Update date:2022-08-03

Topics:

Authors:

Tobe, Yoshito

Ohtani, Masaru

Kakiuchi, Kiyomi

Odaira, Yoshinobu

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Article abstract of DOI:10.1016/S0040-4039(00)88189-7

The Baeyer-Villiger oxidation of exo-7-acetyl<4.2.1>- and exo-7-acetyl<4.2.2>propellanes (2X) and (3X) mainly proceeds via unusual carbocation intermediates to afford the rearranged products.

Full text of DOI:10.1016/S0040-4039(00)88189-7

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