Tetrahedron Letters p. 3865 - 3868 (1983)
Update date:2022-07-31
Topics:
Shimizu, Isao
Ohashi, Yukihiro
Tsuji, Jiro
A new method for α,α-diallylation of ketones catalyzed by palladium-phosphine complexes under neutral conditions has been developed.Allylation of β-keto carboxylates with allylic carbonates, followed by the decarboxylation-allylation as a one-pot reaction affords diallylated ketones in good yields.
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(2006)
