A NEW ONE-POT METHOD FOR α,α-DIALLYLATION OF KETONES BASED ON THE PALLADIUM-CATALYZED REACTION OF ALLYLIC CARBONATES AND ALLYL β-KETO CARBOXYLATES UNDER NEUTRAL CONDITIONS

DOI: 10.1016/S0040-4039(00)94297-7

Source and publish data:

Tetrahedron Letters p. 3865 - 3868 (1983)

Update date:2022-07-31

Topics:

Authors:

Shimizu, Isao

Ohashi, Yukihiro

Tsuji, Jiro

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Article abstract of DOI:10.1016/S0040-4039(00)94297-7

A new method for α,α-diallylation of ketones catalyzed by palladium-phosphine complexes under neutral conditions has been developed.Allylation of β-keto carboxylates with allylic carbonates, followed by the decarboxylation-allylation as a one-pot reaction affords diallylated ketones in good yields.

Full text of DOI:10.1016/S0040-4039(00)94297-7

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