Welcome to LookChem.com Sign In|Join Free

Article Doi

Reactions of Olefin Complexes with Nitrene Precursors. Synthesis of Triazoline and Aziridin Complexes of Palladium(II); Crystal and Molecular Structure of trans-Dichlorobis(11-phenyl-9,10,11-triazabicycloundec-9-ene-N9)palladium-Chloroform(1/2)

DOI: 10.1039/DT9840002409

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2409 - 2414 (1984)

Update date:2022-08-05

Topics:

Authors:

Porta, FrancescaPorta, Francesca

Pizzotti, MaddalenaPizzotti, Maddalena

Monica, Gerolamo LaMonica, Gerolamo La

Finessi, Luis A.Finessi, Luis A.

Cenini, SergioCenini, Sergio

et al.et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9840002409

By reaction at 70 deg C of phenyl azide with a suspension of PdCl2 and cis-cyclo-octene, the complex has been isolated, and its crystal and molecular structure determined.This compound crystallizes in triclinic space group <*> with a=9.258(2), b=10.702(3), c=11.156(2) Angstroem, α=113.94(3), β=99.60(2), γ=104.87(3) deg, and Z=1.The metal lies on a symmetry centre and the complex configuration is trans planar.The chloroform molecules are hydrogen bonded to the co-ordinated chloride ions.The reaction of phenyl azide with cis-cyclo-octene at 70 deg C in the absence of PdCl2 leads to the corresponding anil, N-cyclo-octylideneaniline, .Preformed <2> reacts with phenyl azide in cyclo-octene at 70 deg C to give .By comparison, has been synthesized from the reaction of with N-cyclo-octylideneaniline.

View More

Products guided by the article

Product name:trans-dichlorobis(9-phenyl-9-azabicyclo[6.1.0]nonane)palladium(II)

Cas No:88887-18-7

88887-18-7

R&D Labs maybe for 88887-18-7

Relevant to this article

Hot Product