REGIOSELECTIVE REACTIONS OF ABIETIC ACID METHYL ESTER

DOI: 10.1016/S0040-4020(01)91561-3

Source and publish data:

Tetrahedron p. 3167 - 3170 (1983)

Update date:2022-08-04

Topics:

Authors:

Escudero, Javier

Marquez, Cecilio

Rabanal, Rosa Ma

Valverde, S.

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Article abstract of DOI:10.1016/S0040-4020(01)91561-3

Ozonolysis of abietic acid methyl ester 1 in the presence of mercuric acetate afforded the 13,14-seco-derivative in fair yield (50percent).Selenium dioxide oxidation of 1 in t-butanol gave 9-α-hydroxy-abietic acid methyl ester 6, dehydroabietic acid methyl ester 4 and its 7α-hydroxy-derivative 4b.

Full text of DOI:10.1016/S0040-4020(01)91561-3

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