Stereoselective Acyl Transfer Reactions controlled by the Diphenylphosphinoyl Group: X-ray Structures of Stable Crystalline Silylated Tetrahedral Intermediates

DOI: 10.1016/S0040-4039(00)78217-7

Source and publish data:

Tetrahedron Letters p. 5911 - 5914 (1994)

Update date:2022-08-04

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Authors:

Feeder, Neil

Hutton, Gordon

Warren, Stuart

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Article abstract of DOI:10.1016/S0040-4039(00)78217-7

Acyl transfer with LDA on benzoates of single diastereoisomers of 3-hydroxyalkyldiphenylphosphine oxides in the presence of trimethylsilyl chloride gives silylated tetrahedral intermediates in carbonyl displacement reactions with the stereochemically cont

Full text of DOI:10.1016/S0040-4039(00)78217-7

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