Tetrahedron Letters p. 6133 - 6135 (2001)
Update date:2022-08-05
Topics:
Banert, Klaus
Melzer, Antje
Evidence is presented that the [3,3] sigmatropic rearrangement of simple allyl cyanates to give allyl isocyanates proceeds much more rapidly than the analogous reaction of propargyl cyanates. Nevertheless, a substituted allyl cyanate is isolated for the first time, and the activation parameters of its [3,3] sigmatropic isomerization are measured.
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