CUPRIC ION-CATALYZED DIOXYGENATION OF 1,2-CYCLOHEXANEDIONES. A NONENZYMATIC ANALOG FOR QUERCETINASE DIOXYGENATION

DOI: 10.1246/cl.1984.635

Source and publish data:

Chemistry Letters p. 635 - 638 (1984)

Update date:2022-08-05

Topics:

Authors:

Utaka, Masanori

Hojo, Makoto

Fujii, Yasuyuki

Takeda, Akira

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Article abstract of DOI:10.1246/cl.1984.635

1,2-Cyclohexanediones were found to be dioxygenated by molecular oxygen with the aid of cupric ion to afford 1,5-keto acids and carbon monoxide.The reaction proceeds possibly via an endoperoxide intermediate.Methyl α-hydroxyadipates were also formed as byproducts.The mechanism of oxygenation is discussed.

Full text of DOI:10.1246/cl.1984.635

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