Chemistry Letters p. 635 - 638 (1984)
Update date:2022-08-05
Topics:
Utaka, Masanori
Hojo, Makoto
Fujii, Yasuyuki
Takeda, Akira
1,2-Cyclohexanediones were found to be dioxygenated by molecular oxygen with the aid of cupric ion to afford 1,5-keto acids and carbon monoxide.The reaction proceeds possibly via an endoperoxide intermediate.Methyl α-hydroxyadipates were also formed as byproducts.The mechanism of oxygenation is discussed.
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