Helvetica Chimica Acta p. 538 - 545 (1982)
Update date:2022-08-05
Topics:
Erne, Daniel
Ammann, Daniel
Zhukov, Alex F.
Behm, Felix
Pretsch, Ernoe
Simon, Wilhelm
A sries of lipophilic N,N,N',N'-tetrasubstituted diamides were prepared and their selectivity in solvent polymeric membranes was studied. cis-N,N,N',N'-Tetraisobutylcyclohexane-1,2-dicarboxamide includes a selectivity in membranes for Li+ over alkaline earth metal cations and other alkali metal cations by a factor of about 1000 and 100 respectively.The ionophore N,N'-diheptyl-N,N'-dimethylethylmalonamide is an attractive candidate for the use in microelectrodes for the determination of intracellular Mg2+-activities.
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