Synthetic and Spectroscopic Studies of Phosphoranides - and the Crystal and Molecular Structure of

DOI: 10.1039/DT9900000551

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 551 - 554 (1990)

Update date:2022-08-05

Topics:

Authors:

Deng, Robert M. K.

Dillon, Keith B.

Sheldrick, William S.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9900000551

Several new phosphoranides of the type (R'= Me, Et, Ph, or C6F5; X = Cl, Br, I, or NCS) have been synthesised, and characterised by means of 31P n.m.r. spectroscopy, elemental analysis, and (in some cases) i.r. spectroscopy.These are the first simple phosphoranides to be prepared with an organo group bound directly to phosphorus.Determination of the crystal structure of has shown a monomeric distorted ψ-trigonal bipyramidal geometry for the anion, with the phenyl group equatorial and one very long P-Cl axial bond, as observed previously in the - ion.Halide ions did not form phosphoranides with PBu^t(CN)2, PMe2(CN), or PPh2(CN).

Full text of DOI:10.1039/DT9900000551

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:C₈H₂₀N⁽¹⁺⁾*C₈H₅ClN₂P^(1-)

Cas No:90443-55-3

R&D Labs maybe for 90443-55-3

zonk drug r&d limited

Contact:+86-20-32051076

Address:1105,Building A, International Business Incubator,Science City
Shanghai Bosman Industrial Co., Ltd

Contact:86-21-63065878-8006

Address:Rm907, No.1611, North Sichuan Road, Hongkou District, Shanghai, 200080 China
Shandong Zhongcheng Barium Salt Co., Ltd

Contact:+86-15725732638

Address:No.29 baoxi road, hi-tech zone, zibo, shandong
Kunshan Yalong Trading Co,.Ltd

Contact:86-512-57621185

Address:805-807 Room Hongqiao Mansion ,1088 West Qianjin Road, Kunshan, Jiangsu，China
Hebei Think-Do Environment Co., Ltd

website:http://www.thinkdo-environment.com

Contact:0311-86510809-

Address:No 6, Shilian Middle Street, Circular Chemical Industry Park

Relevant to this article

Stable Gold(I) Complexes with Chelate Rings: Solution Studies of Bis(phosphino)ethane Complexes and X-Ray Crystal Structure of Bis<1,2-bis(diphenylphosphino)ethane>gold(I) Hexafluoroantimonate-Acetone (1/1)

Doi:10.1039/DT9840000969
(1984)
Occurrence of 2 amino 2 deoxy hexuronic acids as constituents of Vibrio parahaemolyticus K15 antigen

Doi:10.1111/j.1432-1033.1973.tb02999.x
(1973)
ASYMMETRIC SYNTHESES VIA METALATED CHIRAL HYDRAZONESOVERALL ENANTIOSELECTIVE α-ALKYLATION OF ACYCLIC KETONES

Doi:10.1016/S0040-4020(01)82420-0
(1984)
Synthesis and Reactions of Some 1-Substituted 1,2-Diazetidinones

Doi:10.1021/jo00197a017
(1984)
Mechanisms of the carbon-hydrogen bond-forming binuclear reductive elimination reactions of benzyl- and hydridomanganese carbonyls

Doi:10.1021/om00120a007
(1985)
Iron-molybdenum charge-transfer hybrids containing organometallic and inorganic fragments bridged by aryldiazenido ligands in a μ- η⁶:η¹ coordination mode: Syntheses, characterization, X-ray structures, electrochemistry, and theoretical investigation

Doi:10.1021/ic0613098
(2007)

Article Doi