A Novel Alkynylation Reaction of Epoxy Alcohols: Use in the Synthesis of erythro-6-Acetoxyhexadecan-5-olide

DOI: 10.1039/c39840000202

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 202 - 203 (1984)

Update date:2022-07-29

Topics:

Authors:

Yamaguchi, Masahiko

Hirao, Ichiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39840000202

Lithium acetylides in the presence of BF3*Et2O react with epoxy alcohols derived from (E)-allylic alcohols to give erythro-1,2-diols, a reaction used successfully in the stereoselective synthesis of erythro-hexadecan-5-olide.

Full text of DOI:10.1039/c39840000202

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(4S,5S)-1-Phenyl-oct-1-yne-4,5-diol

Cas No:90454-67-4

R&D Labs maybe for 90454-67-4

Rudong Zhenfeng Yiyang Chemical Co., Ltd.

Contact:0513-84573047

Address:South Fengli Town, Rudong County, Jiangsu Province, China
Santow Laboratory Limited

Contact:+86-371-55981030

Address:Room 1571, Macalline Soho, No.1, Shangdu Road, Zhengzhou, Henan
Zhangjiagang Golden Reach Fine Chemical Co.,LTD.

Contact:+86-512-6585 6968

Address:Changfu Road， Dongsha Chemical Industry Park, Zhangjiagang City, Jiangsu Province, China
SHANDONG QINGYUNCHANGXIN CHEMICAL SCIENCE-TECH CO.,LTD

Contact:86-21-60560171

Address:1689Donghuan Rade,Qingyun County, Dezhou City, Shandong,China
SHANDONG QINGYUNCHANGXIN CHEMICAL SCIENCE-TECH CO.,LTD

Contact:86-21-60560171

Address:1689Donghuan Rade,Qingyun County, Dezhou City, Shandong,China

Relevant to this article

2' AND 3'-KETONUCLEOSIDES AND THEIR ARABINO AND XYLO REDUCTION PRODUCTS CONVENIENT ACCESS VIA SELECTIVE PROTECTION AND OXIDATION OF RIBONUCLEOSIDES

Doi:10.1016/0040-4020(84)85111-X
(1984)
Doi:10.1021/jo01058a033
(1962)
Synthesis of enantiopure 1-substituted, 1,2-disubstituted, and 1,4,5-trisubstituted imidazoles from 1,2-amino alcohols

Doi:10.1016/j.tet.2006.05.079
(2006)
Azine synthesis via nitrogen-nitrogen bond formation

Doi:10.1080/00397919209409260
(1992)
Manganese dioxide in a new role of Sulfur extrusion in thioamides

Doi:10.1016/S0040-4020(01)88517-3
(1992)
Doi:10.1021/jo01030a011
(1964)

Article Doi