METAL CATALYZED CROSS-COUPLING REACTIONS OF CARBANIONS α TO SILAFUNCTIONAL GROUPS. NEW α-HYDROXYALKYL ANION EQUIVALENTS

DOI: 10.1016/S0040-4039(01)90073-5

Source and publish data:

Tetrahedron Letters p. 1909 - 1912 (1984)

Update date:2022-07-30

Topics:

Authors:

Tamao, Kohei

Iwahara, Takahisa

Kanatani, Ryuichiro

Kumada, Makoto

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Article abstract of DOI:10.1016/S0040-4039(01)90073-5

Carbanions α to (alkoxy)silyl or (amino)silyl groups act as nucleophilic α-hydroxyalkylating agents for organic halides and epoxides via the metal catalyzed coupling reaction and the subsequent oxidative cleavage of the carbon-silicon bond.

Full text of DOI:10.1016/S0040-4039(01)90073-5

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