Journal of the American Chemical Society p. 14325 - 14336 (2006)
Update date:2022-09-26
Topics: Substrate Incorporation Biosynthetic origin glycolate ansamitocin
Wenzel, Silke C.
Williamson, Rachel M.
Gruenanger, Christian
Xu, Jun
Gerth, Klaus
Martinez, Rodolfo A.
Moss, Steven J.
Carroll, Brian J.
Grond, Stephanie
Unkefer, Clifford J.
Mueller, Rolf
Floss, Heinz G.
Feeding experiments with isotope-labeled precursors rule out hydroxypyruvate and TCA cycle intermediates as the metabolic source of methoxymalonyl-ACP, the substrate for incorporation of "glycolate" units into ansamitocin P-3, soraphen A, and other antibi
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