OXIDATION OF AZULENE DERIVATIVES. AUTOXIDATION OF 4,6,8-TRIMETHYLAZULENE IN A POLAR APROTIC SOLVENT

DOI: 10.1246/cl.1984.631

Source and publish data:

Chemistry Letters p. 631 - 634 (1984)

Update date:2022-08-04

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Authors:

Matsubara, Yoshiharu

Takekuma, Shin-ichi

Yokoi, Katsumi

Yamamoto, Hiroshi

Nozoe, Tetsuo

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Article abstract of DOI:10.1246/cl.1984.631

Autoxidation of 4,6,8-trimethylazulene at 120 deg C in N,N-dimethylformamide yielded twelve separable products (including four known compounds), which were assigned to be azulenoquinone, inden-1-one, and azulenyl-1-indanone derivatives.A comparison of the present results with those of guaiazulene was made to obtain a mechanistic aspect of the oxidation reaction.

Full text of DOI:10.1246/cl.1984.631

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