
Tetrahedron Letters p. 1543 - 1546 (1984)
Update date:2022-08-03
Topics: Claisen Rearrangement Vicinal Quaternary centers carbanion
Denmark, Scott E.
Harmata, Michael A.
The preparation and Claisen rearrangement of highly substituated allyl vinyl ethers is described.It is demonstrated that the thermal and anionic versions of the Claisen rearrangement are capable of creating vicinal quaternary centers.
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