Journal of Organic Chemistry p. 4086 - 4087 (1984)
Update date:2022-08-05
Topics:
Zefirov, Nikolai S.
Koz'min, Anatoly S.
Sorokin, Viktor D.
Chlorine and sulfur trioxide combine in methylene chloride at -78 deg C to form chlorine chlorosulfate (1), a highly electrophilic reagent which adds to olefins to form β-chloroalkyl chlorosulfates 2 (both Markovnikov and anti-Markovnikov adducts).
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