Displacive Transfer of a Phenyl Group from Triphenylphosphine to a Metal Atom: Synthesis and Molecular Structure of Ru2Ph2(PhCONH)22

DOI: 10.1021/ja00333a052

Source and publish data:

Journal of the American Chemical Society p. 6409 - 6413 (1984)

Update date:2022-07-30

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Authors:

Chakravarty, Akhil R.

Cotton, F. Albert

Tocher, Derek A.

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Article abstract of DOI:10.1021/ja00333a052

The reaction of Ru2(O2CCH3)4Cl with excess molten benzamide, PhCONH2, affords Ru2(PhCONH)4Cl (1).This reacts with triphenylphosphine in Me2SO-MeOH to generate the title compound, 2, as a brown crystalline solid, insoluble in common solvents.Compound 2 was

Full text of DOI:10.1021/ja00333a052

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