Tetrahedron p. 1791 - 1794 (1984)
Update date:2022-08-05
Topics:
Tamaru, Y.
Yamada, Y.
Ochiai, H.
Nakajo, E.
Yoshida, Z.
Diastereoisomeric mixtures of 2-substituted 1-vinylcyclohexyl acetates (or benzoates) are rearranged stereoselectively to 2-substituted (E)-β-acetoxy (or benzoyloxy)ethylidenecyclohexanes by the catalysis of bis(acetonitrile)palladium(II) chloride.A mechanism related to the stereoselectivity and reactivity is discussed in terms of the conformational requirements in a transition state.
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