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installation of polyfluoroaryls with variable F-content and F-
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good compatibility of functional groups. Our strategy might be
extended to the coupling of Zn-ArF reagents with alkyl radicals
generated by other methods, leading to new methods in
polyfluoroarylation.
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This work is supported by the Swiss National Science Foundation
through the project 200021_181977, and NCCR Catalysis, a
National Centre of Competence in Research funded by the Swiss
National Science Foundation. We thank Prof. Jérôme Waser and
Stephanie Amos (EPFL) for providing the derivatives of 4CzIPN
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Keywords: aliphatic acid • polyfluoroarylation • copper •
photocatalysis • reaction mechanisms
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