Ring Opening Reactions of 1-Ph2PCH2PPh2)(η2-Ph2PCH2PPh2)> M = Cr, Mo, or W with Rh or Ir Complexes to give Bimetallic Systems: Synthesis of

DOI: 10.1039/c39840000933

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 933 - 934 (1984)

Update date:2022-09-26

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Authors:

Blagg, Adrian

Cooper, Gary R.

Pringle, Paul G.

Robson, Richard

Shaw, Bernard L.

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Article abstract of DOI:10.1039/c39840000933

Complexes of the type <(OC)3M(μ-Ph2PCH2PPh2)2M'X(CO)> or <(OC)3M(μ-Ph2PCH2PPh2)2M'(CO)2>+PF6^- have been made either as described in the title or by a ring opening reaction of 2-Ph2PCH2PPh2)2>Cl (M' = Rh or Ir) with a labile Cr, Mo, or W carbonyl derivative: the first bimetallic complex of Ph2PNHPPh2 is described.

Full text of DOI:10.1039/c39840000933

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