Journal of Organic Chemistry p. 3952 - 3954 (2007)
Update date:2022-09-26
Topics:
Du, Yuguo
Liu, Jun
Linhardt, Robert J.
(Chemical Equation Presented) (±)-Paeonilide, a novel monoterpenoid metabolite from the roots of Paeonia delavayi showing anti-platelet activating factor activity, is convergently synthesized in five steps with 59% overall yield. The application of benzoyl peroxide-promoted radical addition of unsaturated ester to aldehyde and subsequent topologically favored cyclization greatly simplified the synthesis.
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Doi:10.1055/s-2007-977456
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