Journal of Organic Chemistry p. 1467 - 1470 (1985)
Update date:2022-08-03
Topics:
Jaeger, David A.
Wyatt, Jacqueline R.
Robertson, Raymond E.
The effect of chain length on the regioselectivity and rate of monochlorination of C6H5OR (1: a = n-C5H11; b, R = n-C9H19; c, R = n-C12H25) with Cl2 in micellar sodium dodecyl sulfate was determined.On going from 1a to 1b to 1c, only modest changes were observed in the para/ortho product ratio and in relative rate.These results were interpreted to indicate that the hydrophilic character of C6H5O dominates the lipophilic character of R in the micellar reactivity of the ethers.
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