Angewandte Chemie - International Edition p. 6670 - 6673 (2007)
Update date:2022-08-05
Topics: Intramolecular cyclization Product Formation Chirality transfer Substrate Gold(I) Catalyst Activation
Tarselli, Michael A.
Chianese, Anthony R.
Lee, Stephen J.
Gagne, Michel R.
(Chemical Equation Presented) Coming around: Cycloisomerization of eneallenes by cationic gold(I) catalysts produces vinylcyclohexene derivatives in up to 77% ee, using [3,5-xylylbinap-(AuCl)2] and AgOTf additive (see scheme; 3,5-xylyl-binap =
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