Tetrahedron p. 13847 - 13856 (1994)
Update date:2022-08-02
Topics: Selectivity Kinetics Olefins Radical Addition Homolytic Cleavage Radical Initiator Spectroscopic Analysis Oxidation state Mechanistic study Reaction yield Ultrasound Mn(III) Cavitation Sonochemistry
Bosman, Cesare
D'Annibale, Andrea
Resta, Stefano
Trogolo, Corrado
Amidoalkyl radicals, generated from amides by Mn(OAc)3 in acetic acid react with phenyl substituted alkenes to generate five-membered lactones or lactams.Ultrasound at ambient temperature significantly accelerates these single electron transfer reactions
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