General Method for Generation of 3-Siloxyallylmetallic Species and Their Synthetic Application

DOI: 10.1021/ja00305a028

Source and publish data:

Journal of the American Chemical Society p. 5495 - 5501 (1985)

Update date:2022-08-04

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Authors:

Enda, Jun

Kuwajima, Isao

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Article abstract of DOI:10.1021/ja00305a028

On treatment with vinylmagnesium bromide, most of the α-branched acyltrimethylsilanes initially from the corresponding 1-(trimethylsilyl)allylic alkoxides, which undergo a facile rearrangement of the silyl group form carbon to oxygen to generate 3-(trimet

Full text of DOI:10.1021/ja00305a028

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