97731-55-0Relevant academic research and scientific papers
General Method for Generation of 3-Siloxyallylmetallic Species and Their Synthetic Application
Enda, Jun,Kuwajima, Isao
, p. 5495 - 5501 (1985)
On treatment with vinylmagnesium bromide, most of the α-branched acyltrimethylsilanes initially from the corresponding 1-(trimethylsilyl)allylic alkoxides, which undergo a facile rearrangement of the silyl group form carbon to oxygen to generate 3-(trimet
Me3SiCl ACCELERATED CONJUGATE ADDITION OF STOICHIOMETRIC ORGANOCOPPER REAGENTS
Nakamura, Eiichi,Matsuzawa, Satoshi,Horiguchi, Yoshiaki,Kuwajima, Isao
, p. 4029 - 4032 (2007/10/02)
Chlorotrimethylsilane, particularly if combined with hexamethylphosphoric triamide or 4-dimethylaminopyridine, strongly promote the conjugate addition of stoichiometric organocopper reagents.
