COMBINATION CLAISEN-NITRILE OXIDE ANNULATION. A STRATEGY FOR RING CONSTRUCTION WITH RIGID STEREOCONTROL DICTATED BY AN ALLYLIC HYDROXYL GROUP.

DOI: 10.1016/S0040-4039(00)94771-3

Source and publish data:

Tetrahedron Letters p. 2031 - 2034 (1985)

Update date:2022-08-05

Topics:

Authors:

Curran, Dennis P.

Jacobs, Patricia B.

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Article abstract of DOI:10.1016/S0040-4039(00)94771-3

A new method for annulation of rings onto existing allylic alcohol derivatives is presented.The sequence involves Claisen rearrangement followed by nitrile oxide-olefin cycloaddition.Control of relevant stereochemistry is emphasized.

Full text of DOI:10.1016/S0040-4039(00)94771-3

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