Journal of the Chemical Society - Faraday Transactions p. 3643 - 3646 (1996)
Update date:2022-08-17
Topics:
Hansen, Keith C.
Lin, Qing
Aminabhavi, Tejraj M.
The kinetics of ruthenium catalysed oxidation of styrene and substituted styrenes by sodium hypochlorite solution was investigated using gas chromatography. The substituted styrenes used were p-methoxystyrene, p-methylstyrene, p-bromostyrene and m-nitrostyrene. It was found that the reaction rates increased from p-methoxystyrene to m-nitrostyrene. The rate constants showed that an electron donating group slowed the rate of reaction while an electron withdrawing group increased the rate of the reaction. The rate constants did not give a good linear relationship with the Hammett substituent constants when correlation with the Hammett equation was attempted. On the other hand, this trend was consistent with the results of analysis by the frontier molecular orbital theory, in which the activation energy of a reaction was correlated with the energy difference between the HOMO of the substituted styrenes and the LUMO of ruthenium tetroxide.
View MoreCompro Shijiazhuang Fine Chemical Co., Ltd
Contact:0086-311-89689838
Address:Economic and Technological Development Zone of Shijiazhuang,Hebei
AUSHUN PHARMACEUTICAL TECHNOLOGY CO,.LTD
Contact:+86-25-86883560 15951806178
Address:14 Dayingbi, Zhujiang Rd. East, Nanjing, Jiangsu, China.
Jiangsu Feymer Technology Co., Ltd.
Contact:+86-512-58110132
Address:Fenghuang Town, Zhangjiagang City, Jiangsu Province, China
Chengdu Aslee Biopharmaceuticals, Inc
Contact:18608018419
Address:Chengdu Aslee Biopharmaceuticals, Inc
Hangzhou TJM Chemical Trade Co., Ltd
Contact:86-571-88223276 86-13388481653
Address:2221#,Boyuexuan,1860# Binsheng Road,Binjiang District, Hangzhou CityZhejiang Province, 310051, P. R. China
Doi:10.1134/S1070428007100326
(2007)Doi:10.1039/c5ob02100f
(2015)Doi:10.1016/j.ejmech.2019.111940
(2020)Doi:10.1039/c6cc07313a
(2016)Doi:10.1359/jbmr.2002.17.2.301
(1956)Doi:10.1021/ja01205a028
(1946)
