Reaction of RuH2(PMe3)4 with benzaldehyde. Formation of novel oxametallacycle and metallacycloketone complexes via C-H bond activation of aldehyde

DOI: 10.1016/0022-328X(94)80127-4

Source and publish data:

Journal of Organometallic Chemistry p. 265 - 272 (1994)

Update date:2022-08-11

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Authors:

Ozawa, Fumiyuki

Yamagami, Isao

Yamamoto, Akio

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Article abstract of DOI:10.1016/0022-328X(94)80127-4

The PMe3-coordinated ruthenium dihydride complex RuH2(PMe3)4 (1) reacted with PhCHO in toluene at -20 deg C to give an oxaruthenacycle complex (2) and 1 equivalent of PhCH2OH.The same reaction carried out at elevated temperatures, on the other hand, affor

Full text of DOI:10.1016/0022-328X(94)80127-4

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