Chemistry Letters p. 19 - 20 (1996)
Update date:2022-08-29
Topics:
Minakata, Satoshi
Imai, Eiichiroh
Ohshima, Yasuhito
Inaki, Kanako
Ryu, Ilhyong
Komatsu, Mitsuo
Ohshiro, Yoshiki
Treatment of benzyl ethyl ether with a catalytic amount of binuclear copper(II) complex of 7-azaindole 1 under oxygen atmosphere at 80 °C produced ethyl benzoate in 10400% yield based on the catalyst. This reaction could be also applied to other ethers (e.g., alkyl benzyl ethers and dialkyl ethers) to give α-oxygenated products catalytically.
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