Journal of the Chemical Society. Chemical communications p. 356 - 358 (1988)
Update date:2022-08-22
Topics:
Page, Philip C. Bulman
Rayner, Christopher M.
Sutherland, Ian O.
The catalysis of the isomerisation of primary cis-2,3-epoxy alcohols to threo-1,2-epoxy alcohols by lithium chloride in tetrahydrofuran solution is described; the more reactive terminal epoxides may be selectively trapped in situ by reaction with nucleophiles, and this methodology is used in an enantioselective synthesis of (+)-exo-brevicomin.
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