Asymmetric Synthesis of 2-Aryl Substituted Oxetanes by Enantioselective Reduction of β-Halogenoketones using Lithium Borohydride modified with N,N'-Dibenzoylcystine

DOI: 10.1039/c39860001018

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1018 - 1019 (1986)

Update date:2022-08-16

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Authors:

Soai, Kenso

Niwa, Seiji

Yamanoi, Takashi

Hikima, Hitoshi

Ishizaki, Miyuki

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Article abstract of DOI:10.1039/c39860001018

Optically active 2-aryl substituted oxetanes are synthesised in high enantiomeric excesses (up to 89percent e.e.) via enantioselective reduction of β-halogenoketones with lithium borohydride using (R,R')-N,N'-dibenzoylcystine and t-butyl alcohols as ligands.

Full text of DOI:10.1039/c39860001018

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