Regioselection and enantioselection in organolanthanide-catalyzed olefin hydrosilylation. A kinetic and mechanistic study

DOI: 10.1021/ja00132a015

Source and publish data:

Journal of the American Chemical Society p. 7157 - 7168 (1995)

Update date:2022-08-17

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Authors:

Fu, Peng-Fei

Brard, Laurent

Li, Yanwu

Marks, Tobin J.

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Article abstract of DOI:10.1021/ja00132a015

This contribution describes a study of scope, regioselection, enantioselection, metal and ancillary ligand effects, and kinetics in the catalytic PhSiH₃ hydrosilylation of olefins using the organolanthanide precatalysts Cp′₂-LnCH(SiM

Full text of DOI:10.1021/ja00132a015

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