
Journal of Organometallic Chemistry p. 269 - 274 (1992)
Update date:2022-08-30
Topics:
Lin, Yingrui
Zhu, Xianchao
Zhou, Yuefen
Transition metal polyhydrides-catalyzed oxidative condensation of diols to 5 and 6-ring lactones was studied.The regioselective dehydrogenation of unsymmetrically substituted 1,4-diols gave β- or γ-substituted γ-lactones in high yields.The mechanism of dehydrogenation under neutral and mild conditions was discussed.
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