Tetrahedron Letters p. 349 - 351 (2003)
Update date:2022-08-16
Topics:
Stratakis, Manolis
Rabalakos, Constantinos
Sofikiti, Nikoletta
Triaryl phosphites selectively reduce aryl selenoxides to selenides. The Hammett plot of the reactions of para-phenyl substituted triaryl phosphites with diphenyl selenoxide gave ρ=+2.3, whereas with bis(p-methoxyphenyl) selenoxide, ρ=-2.1. The results are consistent with a concerted mechanism for the oxygen transfer from Se to P.
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