Journal of the Chemical Society. Chemical communications p. 1523 - 1524 (1985)
Update date:2022-08-17
Topics:
Aly, Moustafa F.
Grigg, Ronald
α-Keto acids are readily decarboxylated via imine formation with primary and/or secondary amines even when imine-enamine isomerisation can occur; the process is thought to involve an intermediate zwitterion which can be trapped by sulphur to give thioamides in excellent yield.
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