One-electron Oxidation of Carboxylates by Hexachloroosmate(V) Ion

DOI: 10.1039/c39920001041

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1041 - 1042 (1992)

Update date:2022-08-23

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Authors:

Eberson, Lennart

Nilsson, Monica

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Article abstract of DOI:10.1039/c39920001041

Hexachloroosmate(V) cleanly oxidizes tetrabutylammonium tert-butylcyanoacetate to decarboxylative-coupling products, meso- and rac-2,3-di-tert-butylsuccinonitrile, thus constituting the first metal ion-based oxidant to be found to simulate properly this aspect of the Kolbe anodic oxidation of carboxylates.

Full text of DOI:10.1039/c39920001041

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