Carbon-Carbon Bond Formation via Opening of Epoxysilanes with Organometals Containing Lithium and Copper

DOI: 10.1021/jo00270a009

Source and publish data:

Journal of Organic Chemistry p. 2043 - 2044 (1989)

Update date:2022-08-25

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Authors:

Zhang, Yantao

Miller, Joseph A.

Negishi, Ei-ichi

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Article abstract of DOI:10.1021/jo00270a009

Various types of organometals containing lithium and copper react with E and Z epoxysilanes to produce adducts which, either under the reaction conditions or upon treatment with a base, e.g., KH, can be stereospecifically converted to the corresponding E and Z alkenes, respectively.

Full text of DOI:10.1021/jo00270a009

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