Tetrahedron Letters p. 4919 - 4922 (1996)
Update date:2022-08-11
Topics:
Connolly, Terrence J.
Baldovi
Mohtat
Scaiano
Two photochemical routes to stoichiometric initiators used in living free radical polymerizations are presented. These routes offer the advantages of higher yields and allow for the preparation of initiators not accessible using current methodology. All initiators gave detectable carbon centered radicals (laser flash photolysis) and promoted the polymerization of styrene.
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