
Inorganic Chemistry p. 989 - 992 (1966)
Update date:2022-08-11
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Anderson
A new synthesis is described for preparation of boron nitride from the reaction of an alkyl polyborate-ammonia complex (RO)3B25O36·(NH3)8 with ammonia in the temperature range of 400-800°. The ammonia complex is obtained via a novel disproportionation of a trialkoxyboroxine to the corresponding trialkoxyborane and the ammonia complex. Boron nitride obtained under these conditions possesses a turbostratic structure.
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Doi:10.1039/CT9191501168
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