Chemistry of Heterocyclic Compounds p. 294 - 307 (1996)
Update date:2022-08-11
Topics:
Iovel'
Rubina
Popelis
Gaukhman
Lukevits
A study has been made of enantioselective hydrosilylation and reduction, by hydrogen transfer, of prochiral alkyl phenyl ketones or alkyl hetaryl ketones over various optically active catalysts. A total of 14 aromatic and heterocyclic carbinols were synthesized with preparative yields of 54-100%. The most effective catalytic systems were found to be complexes of RhCl3 and [Rh(cod)Cl]2 with the known optical inductor (S,S)-i-Pr-Pybox, with which we have obtained for the first time a series of heterocyclic secondary alcohols with an enantioselectivity of 20-63%. 1996 Plenum Publishing Corporation.
View More
GUANGZHOU MEDCAN PHARMATECH LTD
website:http://www.gzmedcan.com
Contact:+86-20-82519649
Address:Building J,Room 101,1 JiangtashanRd,Guang Zhou Science City,Guang Zhou ,China
Contact:+86-21-38228826
Address:Room 505 Building 2, No 3377 Kangxin Highway, Shanghai, Republic China
SHIJIAZHUANG CHENSHI IMPORT AND EXPORT CO.,LTD
Contact:+86-311-89871056
Address:RM2017 BUILDING CTIANSHAN GALAXY PLAZA,NO168 CHANGJIANG ROAD,GAOXIN DISTRICT,SHIJIAZHUANG CITY, HEBEI,CHINA
Baoding City Light Industry And Textiles Imp.& Exp. Corp. Chemical Department.
Contact:86-312-3262436
Address:NO.658 CHAOYANG SOUTH STREET,BAODING CITY HEBEI CHINA
website:http://www.greenutra.cn
Contact:0086-411-39553357
Address:No. 7-1-1802, Huizhi Garden,Ocean Square,Dalian, 116033, China
Doi:10.1021/jacs.7b13701
(2018)Doi:10.1016/0040-6031(88)87002-3
(1988)Doi:10.1016/j.bioorg.2021.105136
(2021)Doi:10.1016/j.bmcl.2008.10.063
(2008)Doi:10.1016/j.cclet.2016.12.037
(2017)Doi:10.1021/acs.orglett.6b03692
(2017)
